SAEED MDCAT
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In thermodynamic, which one of the following is not a state function?
Work is not a state function but entropy(S), internal energy (E) and Gibb’s free energy(G) are state functions.
Work is not a state function but entropy(S), internal energy (E) and Gibb’s free energy(G) are state functions.
The environment in which a system is studied is
The environment except system is called surrounding
The environment except system is called surrounding
Work may be defined in terms of pressure-volume as
Work is taken as PV
Work is taken as PV
Which of the following process may be exothermic
1st electron affinity(E.A) is exothermic process. 1st E.A value may be exothermic but 2nd E.A and 1st I.P or higher I.P values are endothermic.
1st electron affinity(E.A) is exothermic process. 1st E.A value may be exothermic but 2nd E.A and 1st I.P or higher I.P values are endothermic.
Which of the following enthalpy change (∆Hº) is always endothermic
Heat of atomization is always endothermic ∆Hºata. Enthalpy of formation(DH°f) = May be endothermic (+ve) or exothermic (-ve)b. Enthalpy of solution (DH°sol) = May be endothermic (+ve) or exothermic (-ve)c. Enthalpy of atomization (DH°at) = Always endothermic (+ve)d. Enthalpy of neutralization(DH°n) = Always exothermic (-ve)
Heat of atomization is always endothermic ∆Hºata. Enthalpy of formation(DH°f) = May be endothermic (+ve) or exothermic (-ve)b. Enthalpy of solution (DH°sol) = May be endothermic (+ve) or exothermic (-ve)c. Enthalpy of atomization (DH°at) = Always endothermic (+ve)d. Enthalpy of neutralization(DH°n) = Always exothermic (-ve)
A reaction gives out heat. This means that
When bond formation energy is highs than bond breakage, then heat gives out i.e. exothermic Reaction in which heat evolves is called
When heat value reaction exothermic
When heat value reaction exothermic
All types of energies of particles forming a system is called
All types of energies of particles forming a system is called Internal energy
All types of energies of particles forming a system is called Internal energy
The amount of heat required to raise the temperature of a body through 10C is called
The amount of heat required to raise the temperature of a body through 10C is called Heat capacity
The amount of heat required to raise the temperature of a body through 10C is called Heat capacity
There are how many conventional ways to change the internal energy of system
The two ways to change the internal energy of system. The energy can be exchanged between system and surrounding only in the form of work and energy.First law of thermodynamics
The two ways to change the internal energy of system. The energy can be exchanged between system and surrounding only in the form of work and energy.First law of thermodynamics
The expression E = q + w is
The expression E = q + w is First law of the thermodynamics
The expression E = q + w is First law of the thermodynamics
An enthalpy change which is always exothermic
H°at = Endothermic
H°n = Exothermic
H° solution = Exothermic, Endothermic
H°f = Exothermic, Endothermic
H°at = Endothermic
H°n = Exothermic
H° solution = Exothermic, Endothermic
H°f = Exothermic, Endothermic
In a chemical reaction, if products are less stable then
In endothermic process product are less stable than reactant.
In endothermic process product are less stable than reactant.
Change in enthalpy of DH of a gaseous system can be calculated by following relationship
Change in enthalpy of DH of a gaseous system can be calculated by following relationship
Change in enthalpy of DH of a gaseous system can be calculated by following relationship
Standard enthalpies of formation of O3, CO2, NH3 and HI are 142.2, -393.3, -46.2 and +25.9 kJ mol-1 respectively. The order of their increasing stabilities will be
Amount of released energystability
Amount of released energystability
Which one of the following reactions represent both standard enthalpy of combustion as well as standard enthalpy of formation
1 mole of CO2 formation is only
1 mole of CO2 formation is only
Which of the following values of heat of formation indicates that the product is most stable.
That change is the most stable in which product has low energy than the reactant.
That change is the most stable in which product has low energy than the reactant.
The condition for standard enthalpy change are
The condition for standard enthalpy change are 1 atm and 25 °C
The condition for standard enthalpy change are 1 atm and 25 °C
Which of the following is incorrect about enthalpy of neutralization
Energy is always released in neutrilizaiton.
Energy is always released in neutrilizaiton.
The enthalpy of formation of an ionic compound is -392 Kj / mol. Total energy changes (Hx ) involved in the formation of gaseous ions form normal physical state is 280 kJ / mole. The enthalpy of lattice (
Hlatt .) is
Which one indicates the H°f of ionic compounds
is the correct expression of enthalpy of formation
is the correct expression of enthalpy of formation
Lattice energies are helpful in discussing the ————————– of ionic compounds.
From lattice energy we discuss the structure , bonding and properties of ionic compound. Greater the lattice energy stable is the structure and stronger is the bonding.
From lattice energy we discuss the structure , bonding and properties of ionic compound. Greater the lattice energy stable is the structure and stronger is the bonding.
Hess’s law is applicable for the determination of enthalpy of
Hess’s law is applicable to measure enthalpy of reaction, formation and lattice energy
Hess’s law is applicable to measure enthalpy of reaction, formation and lattice energy
Consider the following reactionsN2 +2O2 →2NO2 ∆H = 92kJ 2NO +O2 →2NO2 ∆H = -158kJCalculate the enthalpy of reaction of NON2 +O2 → 2NO ∆H = kJ
Based on the following reactions C(graphite) + O2 → CO2(g) , →H = –394 kJ/mole and 2CO(g)+O2(g) →2CO2(g), H = –569 kJ/ mol, the heat of formation of CO will be
The net change in energy in a chemical reaction is same whether it takes place directly or indirectly. It is called
The net change in energy in a chemical reaction is same whether it takes place directly or indirectly. It is called Hess’s law
The net change in energy in a chemical reaction is same whether it takes place directly or indirectly. It is called Hess’s law
Find the oxidation state of ‘S’ in H 2SO4
2H + S + 4O = 02 + S + (-8) = 0S -6 = 0S = 6
2H + S + 4O = 02 + S + (-8) = 0S -6 = 0S = 6
The oxidation no. of Cr is___ in K 2Cr2 O 7 or K2 2CrO4 .
2K + 2Cr + 7O = 02Cr + 2 + (-14) = 02Cr = 12Cr = 6
2K + 2Cr + 7O = 02Cr + 2 + (-14) = 02Cr = 12Cr = 6
To balance oxygen in ion electron method in acidic solution, we add
2Cl -1 → Cl2
The charges are balanced in above equation by adding
Net charge on left side is -2 while zero on right side, so 2e– added on the right side
Net charge on left side is -2 while zero on right side, so 2e– added on the right side
In the reaction 2 Fe + 3 Cl2 → 2 FeCl3
Iron (Fe) is oxidized from zero to +3 state.
Iron (Fe) is oxidized from zero to +3 state.
In a reaction, the oxidation number of Cr decreases by 3. This indicates that Cr is
Decrease in oxidation number is reduction
Decrease in oxidation number is reduction
Which is true about the reaction Mg + Cℓ2 → MgCℓ2
Mg is oxidized from 0 to +2
Mg is oxidized from 0 to +2
The direction of flow of electrons through external circuit in electrolytic cell is from
In electrolytic cell the direction of flow of electrons through external circuit is from anode to cathode
In electrolytic cell the direction of flow of electrons through external circuit is from anode to cathode
In the electrolysis of dil H2 SO4 using platinum electrode, what is true
At anode OH-1 is oxidised to O2 due to higher oxidation potential as compare to sulphate ions
At anode OH-1 is oxidised to O2 due to higher oxidation potential as compare to sulphate ions
In an electrolytic cell current flows in external circuit
In an electrolytic cell current flows from anode to cathode outside the cell
In an electrolytic cell current flows from anode to cathode outside the cell
The products of electrolysis of dilute aqueous sodium nitrate are
In case of sodium nitrate, salt remains unchanged and water will be hydrolysed, due lower reduction potential of Na ion as compare to H ion, for anode, OH-1 has higher oxidation potential as compare to nitrate ions.
In case of sodium nitrate, salt remains unchanged and water will be hydrolysed, due lower reduction potential of Na ion as compare to H ion, for anode, OH-1 has higher oxidation potential as compare to nitrate ions.
Which of the following has a spontaneous oxidation-reduction reaction?
Both galvanic cell & voltaic cell have a spontaneous oxidation-reduction reaction.
Both galvanic cell & voltaic cell have a spontaneous oxidation-reduction reaction.
Which of the following factors accounts for degree of dissociation of an electrolyte
Nature of electrolyte, temperature & concentration are the factors for degree of dissociation of an electrolyte
Nature of electrolyte, temperature & concentration are the factors for degree of dissociation of an electrolyte
Temperature for the measurement of standard electrode potential is
25°C =298K
25°C =298K
List of elements based on hydrogen scale is called
List of elements based on hydrogen scale is called Electrochemical series.
List of elements based on hydrogen scale is called Electrochemical series.
The standard reduction potential of Zn is
The standard reduction potential of Zn is –0.76
The standard reduction potential of Zn is –0.76
Select the correct statement about salt bridge
Salt bridge maintain neutrality of solution by transfer of ions from one half cell to other.
Salt bridge maintain neutrality of solution by transfer of ions from one half cell to other.
__________ is not there in all the galvanic cells
(I) Salt bridge (II) electrolyte (III) electrode
Salt bridge is not present in all the galvanic cell. Sometime porous partition may also be used.
Salt bridge is not present in all the galvanic cell. Sometime porous partition may also be used.
Which one of the following is not an inert electrode
Pt and Pd are inert electrodes.
Pt and Pd are inert electrodes.
If Cu(NO3)2 (aq) is electrolysed in presence of an inert electrode, product at cathode and at anode respectively
Cu will be deposited at cathode, oxygen gas will liberate at anode.
Cu will be deposited at cathode, oxygen gas will liberate at anode.
Which gas will be evolved at cathode during electrolysis of aq. CuCl2 solution
At cathode, Cu metal will be deposited so no gas evolves at cathode
At cathode, Cu metal will be deposited so no gas evolves at cathode
Which of the following process will be spontaneous and endothermic
In all process, heat is absorbed, so endothermic
In all process, heat is absorbed, so endothermic
The oxidation no. of Mn in MnO4-2 is
Mn + 4O = -2Mn + (-8) = -2Mn = -2 + 8 = 6
Mn + 4O = -2Mn + (-8) = -2Mn = -2 + 8 = 6
In ion method to balance ‘O’ atoms water molecules added. 2Cl-1 → Cl2 + 2e- is an example of
Lose of electron is oxidation.
Lose of electron is oxidation.
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