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HUZAIFA SAEED
Yield of ammonia in Haber’s process can be increased by all except
Ksp values of four salts are given, which is less soluble in water
Solubility product of a salt AB is 0.25 mol2 / dm6, what will be its solubility (mol/dm3)
Select the buffer which is not acidic
A buffer is prepared by mixing the solutions of equimolar acetic acid and sodium acetate. The pH should be equal to
If number of moles of reactants are equal to those of products, then relationship between Kp and Kc is
In Arrhenius equation k = Ae-Ea/RT, ______ depends upon collision frequency
Difference of energy between reactants and transition state is called
The mechanism below has been proposed for the reaction of CHCl3 with Cl2Step l: Cl2(g) 2Cl(g) fastStep 2: Cl(g) + CHCl3(g)
CCl3(g) + HCl(g) slowStep 3: CCl3(g) + Cl(g)
CCl4(g) fastRate law for the reaction is
Rate of following reaction can be expressed as PCl5 PCl3 + Cl2
In the hydrolysis of an organic chloride in the presence of large excess of waterR3C-Cl + H2O → R3C-OH + HCl, order of reaction is
Which of following statement is correct about zero order reaction
If during reaction, there is rotation in plane polarized light, then its rate can be determined by
One of the following is not a physical method for determination of rate of reaction
1.0g mole of ethyl alcohol and 1.0g mole of acetic acid are mixed. At equilibrium 0.333g mole of the ester is present. The value of equilibrium constant is
Consider a reaction N2 + 3H2 2NH3. Correct relation between Kp and Kc is
Appropriate units of Kp for the following reaction is 2SO3 2SO2 + O2
For 2nd order reaction, rate constant has units
For a reaction like X + 2Y → Z Rate = k [X][Y] 2If concentration of X and Y is doubled, then rate of reaction will increase
Unit of rate of this reaction is
Ionization of phenol can be decreased by adding
If Ksp is greater than the product of concentration of ions at particular temperature, then solution is
The equilibrium constant for the reaction is 1055 at 25 °C, this indicates that
Determine partial pressure of NO at equilibrium if partial pressure of N2 and O2 are 8 and 32 torr respectively (Kp = 1.0) N2 + O2 2NO
Find the Kc of following reaction if equilibrium concentrations of acetic acid, ethanol, ethyl acetate and water are 1.5M, 1.5M, 2.5M and 2.5M respectivelyCH3COOH + CH3CH2OH CH3COOCH2CH3 + H2O
An addition of NH4Cl in NH4OH solution suppresses the concentration of
The order of reaction may be determined by
Half-life of the reaction becomes half when initial concentrations of reactants are doubled. The order of the reaction will be
Following is the condition of reversible reaction that is not affected by pressure (where ∆n = number of moles of product–number of moles of reactants)
For endothermic reaction, the minimum value for the energy of activation will be
Catalyst can change
pH of buffer in which concentrations of salt and base are 0.1M and 0.01M respectively (pKb = 4.0)
Equilibrium position is shifted backward by increasing temperature in all except
Ksp for following can be written as PbCl2 Pb+2+ 2Cl–
Slowest step in the reaction is called
In a reaction, A + B → Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 4 when the concentrations of both the reactants (A and c. are doubled, rate law for the reaction can be written as
The solubility product of PbSO4 is 4 x 10 -6 mol 2. dm -6. The maximum concentration of Pb+2 ions is
The rate of a chemical reaction doubles for every 10°C rise of temperature. If the temperature is raised by 60°C, the rate of the reaction increases by about
Which will change for first order reaction with time
Rate of exothermic reaction is increased by increasing all except
A certain reaction has the rate equation, Rate = k[A][B] 2. The rate is 2.5×10 -3mol dm -3s -1. When [A] is 0.2 mol dm -3 and [B] is 0.050 mol dm -3. Calculate the numerical value of rate constant
Half-life of radioactive isotope is 30days. Days required when 12.5% concentration is left behind
Half-life of certain reaction decreases with decrease in concentration. Order of reaction is
Following is an exothermic reaction. Which is correct statement?
At equilibrium, relationship between concentrations of reactants and products
For the gas phase reaction yield of Z at equilibrium could be increased by
The units of equilibrium constant for the reaction are
For the reaction one starts with 6 moles A and 7 moles B per dm3. When equilibrium is attained, 4.5 moles of C and 4.5 moles of D are formed, what is the value of Kc for the reaction
Potential energy of activated complex for exothermic reaction is
Unit of slope in Arrhenius equation is
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